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CC BY-NC-ND 4.0 · Organic Materials 2021; 3(03): 455-468
DOI: 10.1055/a-1578-0960
DOI: 10.1055/a-1578-0960
Focus Issue: Supramolecular Optoelectronic Materials
Short Review
Excimers in Multichromophoric Assemblies: Boon or Bane?
Abstract
Exciton dynamics in organic semiconductors is a subject of great significance from the standpoint of light emission, as well as light harvesting. As transient excited state species, excimers are expected to play a significant role in the dynamics and the fate of the excited state. Till recently, the discourse on excimers in organic systems revolved around their role in aggregation-induced fluorescence quenching, or utilizing their characteristic red-shifted emission to report local interactions. But in the last decade, research in the area of organic multichromophoric systems has brought the spotlight back on this fascinating species. This review focuses on recent developments that highlight the importance of excimers in various processes involving multichromophoric systems, such as circularly polarized emission, exciton migration, and singlet fission. The review also attempts to address the question of whether excimers are useful or detrimental to various photophysical and photochemical processes of importance.
Table of content:
Introduction
Excimers in Multichromophoric Assemblies
Excimer Luminescence
Excimers in Light Harvesting
Conclusions and Outlook
Key words
excimers - multichromophoric assembly - circularly polarized luminescence - exciton migration - singlet fission - symmetry-breaking charge separationPublikationsverlauf
Eingereicht: 23. Juni 2021
Angenommen: 03. August 2021
Accepted Manuscript online:
03. August 2021
Artikel online veröffentlicht:
30. September 2021
© 2021. The Author(s). This is an open access article published by Thieme under the terms of the Creative Commons Attribution-NonDerivative-NonCommercial License, permitting copying and reproduction so long as the original work is given appropriate credit. Contents may not be used for commercial purposes, or adapted, remixed, transformed or built upon. (https://creativecommons.org/licenses/by-nc-nd/4.0/)
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