Synthesis of New Optically Active d-Glucosamine-Pyrrole Derivatives

Bernardo A. Frontana-Uribe; Martha V. Escárcega-Bobadilla; Jorge Juárez-Lagunas; Rubén A. Toscano; Gustavo A. García de la Mora; Manuel Salmón

doi:10.1055/s-0028-1087968

PAPER

Synthesis of New Optically Active d-Glucosamine-Pyrrole Derivatives

Bernardo A. Frontana-Uribe*^a, Martha V. Escárcega-Bobadilla^a, Jorge Juárez-Lagunas^a, Rubén A. Toscano^a, Gustavo A. García de la Mora^b, Manuel Salmón*^a
^a Instituto de Química, Universidad Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, Coyoacán, 04510, D. F. México City, México
e-Mail: bafrontu@servidor.unam.mx; e-Mail: salmon@servidor.unam.mx;
^b Facultad de Química, Universidad Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, Coyoacán, 04510, D. F. México City, México
Fax: +52(55)56162203;

Abstract

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Abstract

From d-glucosamine hydrochloride was synthesized, for the first time, three new optically active derivatives of d-glucosamine-pyrrole with the pyrrole group unsubstituted in the 2- and 5-positions. New N-benzylpyrrole-d-glucosamine derivatives were also prepared from the same substrate.

Key words

glycosides - heterocycles - pyrroles - chirality - d-glucosamine

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Referenzen

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Crystallographic data for compound 5 were deposited at the Cambridge Crystallographic Data Centre with deposit number CCDC-644070.