Nickel-Catalyzed Cycloaddition between Phthalic Anhydrides
and Allenes

doi:10.1055/s-0030-1260389

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Synfacts 2011(6): 0637-0637
DOI: 10.1055/s-0030-1260389

Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

Nickel-Catalyzed Cycloaddition between Phthalic Anhydrides and Allenes

Contributor(s): Mark Lautens, Stephen G. Newman
Y. Ochi, T. Kurahashi*, S. Matsubara*
Kyoto University, Japan

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Publikationsverlauf

Publikationsdatum:
19. Mai 2011 (online)

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Significance

Allenes are useful partners in metal-catalyzed cycloadditions. The authors present a novel decarbonylative cycloaddition between phthalic anhydrides and allenes, providing interesting heterocycles. By utilizing chiral foxap ligands, moderate to good enantioselectivity can be achieved.