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Synthesis 2023; 55(01): 62-74
DOI: 10.1055/s-0040-1720046
DOI: 10.1055/s-0040-1720046
short review
Transborylation-Enabled Boron Catalysis
S.P.T. thanks the Royal Society for a University Research Fellowship (URF/R/191015). S.P.T., A.D.B., and K.N. thank AstraZeneca and the Engineering and Physical Sciences Research Council (EPSRC) for Ph.D. studentships.
Abstract
This review highlights transborylation (controlled boron-boron exchange) and its applications as a turnover strategy in boron-catalysed methodologies. Catalytic applications of B–C, B–O, B–N, B–F, B–S, and B–Se transborylations are discussed in the context of transborylation-enabled catalysis, across a wide range of organic transformations including hydroboration, C–C bond formation, C–H borylation, chemoselective reduction, and asymmetric reduction.
1 Introduction
2 B–C Transborylation
3 B–O Transborylation
4 B–N Transborylation
5 B–F Transborylation
6 B–S Transborylation
7 Conclusion
Publication History
Received: 05 August 2022
Accepted after revision: 26 August 2022
Article published online:
10 October 2022
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