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Synlett 1994; 1994(8): 589-590
DOI: 10.1055/s-1994-22936
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Introduction of acetylene moiety into amide-carbons via Pd-coupling and its application for a model of dynemicin A

Takaaki Okita* , Minoru lsobe
  • *Laboratory of Organic Chemistry, School of Agriculture, Nagoya University, Chikusa, Nagoya 464-01, Japan
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Publication Date:
18 September 2002 (online)

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An acetylene moiety was introduced to a carbonyl carbon of amide group via its triflate in the presence of catalytic palladium complex. Utilizing this methodology, a model compound of dynemicin A possessing acetylene group was synthesized.