Download PDF
Synlett 1997; 1997(10): 1157-1158
DOI: 10.1055/s-1997-988
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Stereospecific Preparation of (E) and (Z)-3,3-Diarylacrylonitriles by Heck Reaction

Marcial Moreno-Mañas* , Roser Pleixats, Anna Roglans
  • *Department of Chemistry, Universitat Autònoma de Barcelona, Cerdanyola, 08193-Barcelona, Spain, Fax 34 3 5811265; E-mail iqorb@cc.uab.es
Further Information

Publication History

Publication Date:
31 December 2000 (online)

  PDF Download  Permissions and Reprints All articles of this category

Both isomers 5 and 8 of 3,3-diarylacrylonitrile constitution are obtained in highly diastereoselective Pd-catalyzed Heck reactions under Jeffery conditions between (E)-cinnamonitriles and aryl iodides.

Pd catalysis - Heck reaction - phase transfer catalysis - Jeffery conditions