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Synlett 2014; 25(08): 1055-1067
DOI: 10.1055/s-0033-1340668
DOI: 10.1055/s-0033-1340668
account
Ten Years of Adventures with Pd/C Catalysts: From Reductive Processes to Coupling Reactions
Further Information
Publication History
Received: 04 November 2013
Accepted after revision: 11 December 2013
Publication Date:
27 January 2014 (online)
Abstract
This account summarizes ten years of projects in the Felpin group involving Pd/C as a catalyst for cross-coupling reactions. From early studies to recent developments, the story tells of the successes and the failures, and it shows the progress gained in understanding of factors governing the catalytic activity and efficiency of Pd/C catalysts. This account could serve as a textbook for synthetic chemists interested in practical methodologies involving C–C bond formation.
1 Introduction
2 Pd/C: Basic Knowledge
3 Early Studies
4 Homemade Pd/C Catalysts
5 Future Prospects
6 Summary and Outlook
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For reviews on Pd/C, see:
For recent general reviews on Suzuki reactions, see:
For Pd/C-catalyzed coupling reactions with aryl chlorides, see:
For recent general reviews on Heck reactions, see:
For claims of a fully heterogeneous mechanism, see ref. 15b and: