DOI: 10.1055/s-00000131

Synfacts

Ausgabe 05 · Volume 14 · Mai 2018 DOI: 10.1055/s-008-39673

Synform

A66
Zanda, Matteo: SYNFORM ISSUE 2018/05

Synthesis of Natural Products and Potential Drugs

z0445
All PDFs of this category
0445
Total Synthesis of Seven Indole Alkaloids
0446
Total Synthesis of (–)-Chromodorolide B
0447
Synthesis of Fosdevirine
0448
Synthesis of (–)-Xylogranatopyridine B
0449
Total Synthesis of (–)-Divergolide I
0450
Synthesis of CH4930808
0451
Synthesis of Largazole
0452
Synthesis of (–)-Enigmazole A
0453
Synthesis of (–)-Hebelophyllene E
0454
Synthesis of (–)-Tambromycin
0455
Synthesis of GDC-0810
0456
Reductive Amination of β-Tetralones Catalyzed by a Chiral Phosphoric Acid

Synthesis of Heterocycles

z0457
All PDFs of this category
0457
Azepines by a Carbonylative Rhodium-Catalyzed Reaction of Aminocyclopropanes
0458
Xanthates for Radical-Mediated Alkylations of Heteroarenes
0459
Synthesis of 2-(Trifluoromethyl)indoles from 2-Alkynylanilines
0460
Synergistic Rhodium/Gold-Catalysis Approach to Spiroethers
0461
Regioselective Deuterium and Tritium Labeling of Azaarenes
0462
Copper-Catalyzed Synthesis of Fluoroalkylated Isoxazoles
0463
Gold-Catalyzed Synthesis of 4H-Azepines and Pyridines
0464
Iridium-Catalyzed C–H Intramolecular Amidation To Give γ-Lactams
0465
Reactions of a Fluorosulfuryl Cation Donor with Phenols or Amines
0466
Synthesis of Indolizines by Reaction of Pyridines with Allenoates
0467
N-Ring Annelated Furanones by Iron-Catalyzed Cyclic Amine Functionalization
0468
Chiral 3,4-Dihydro-2H-1,4-benzoxazines by Aminohydroxylation of 1,3-Dienes
0469
Synthesis of 2-Azabicyclo[3.2.0]heptanes by [2+2] Photocycloaddition

Synthesis of Materials and Unnatural Products

z0471
All PDFs of this category
0471
All Kinds of Alkynylpyridiniums: Elusive Salts Now Plentiful
0472
Dynamic Molecular Cage of Corannulane
0473
peri-Annulation for Polyaromatic Hydrocarbons
0474
Unveil the Mystery of Cross-Linked Polydicyclopentadiene
0475
Unconventional Insertion of Phosphines into Disulfides
0476
A Fluorescent Macrocycle with a Bright Future
0477
Multi-Responsive Amino-Borane Chromophore
0478
Silver Switches Helicity in Homochiral Bis-sulfoxide Foldamer
0479
Fluorescent L-Shaped Heteroarenes from Carbodiimide
0480
Mechanofluorochromic Materials from Transient-Ligand-Enabled Arylation
0481
Functional Polymers by Closing One Ring and Opening the Rest
0482
Don’t Taste this Rainbow: A Spectrum of Mechanochromic Polymers

Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

z0483
All PDFs of this category
0483
Titanium-Catalyzed Stereoselective Formal [3+2] Cycloaddition
0484
Palladium-Catalyzed Atroposelective C–H Alkynylation of Biaryl Aldehydes
0485
Iron(III)–Salan Complex Catalyzed Enantioselective α-Chlorination
0486
Rhodium-Catalyzed Enantioselective Synthesis of Branched 1,4-Enynes
0487
Enantioselective Electrophilic Amination of Ketones
0488
Palladium-Catalyzed Asymmetric Regioselective Addition Reaction of Indoles
0489
Iridium-Catalyzed Allylic Alkylation of Hydroxyquinolines
0490
Palladium-Catalyzed Enantioselective Intermolecular Allylic Dearomatization
0491
Asymmetric Nickel-Catalyzed Allylic Alkylation
0492
Enantioselective Doyle–Kirmse Reaction
0493
Tsuji–Trost Reaction of Allylic Alcohols
0494
Synthesis of Chiral Alcohols by Sequential Hydration–Hydrogenation
0495
Ligand Enabled γ-Selective C–H Activation of Ketones
0496
Asymmetric Dearomative [3+2] Cycloaddition Reactions
0497
Asymmetric Hydrogenation of 2-Arylpyridinium Salts
0498
Asymmetric Synthesis of Homopropargylic Alcohols
0499
Stereoselective Trifluoromethylation and Difluoroalkylation Reactions
0500
Copper-Catalyzed Enantioselective Synthesis of Benzofuroindolines
0501
Copper-Catalyzed Hydroboration of 1,3-Enynes: Access to Chiral Allenyl-B(pin)
0502
Rhodium-Catalyzed Enantioselective Allylation of Triazoles with Internal Alkynes
0503
Rhodium-Catalyzed Asymmetric Synthesis of α-Propargyl-β-Hydroxy Ketones
0504
Ruthenium-Catalyzed Reductive Amination To Form Chiral Amines
0505
Enantioselective Synthesis of the Spirotropanyloxindole Scaffold
0506
Sc–Catalyzed Enantioselective Michael Addition of Tryptamine-Derived Oxindoles to Alkynones
0507
Dynamic Kinetic Resolution of Heterobiaryl Ketones
0508
Visible-Light Photoredox-Catalyzed Stereospecific Synthesis of Aziridines
0509
Conjugate Addition Reactions Catalyzed by a Chiral-at-Metal Rhodium(III) Complex
0510
Palladium-Catalyzed Arylation of Sulfenate Anions: Access to Chiral Sulfoxides
0511
Enantioselective Rhodium-Catalyzed Formal [4+2] Cycloaddition
0512
Asymmetric Ring-Opening of Heterobicyclic Alkenes with Anilines

Metal-Mediated Synthesis

z0513
All PDFs of this category
0513
Convenient Synthesis of Tertiary Amines
0514
Alkylations of Lithiated 4-Alkoxyalk-4-ene-nitriles
0515
Arylation of Ambiphilic α-Bromoalkyl Boronic Esters
0516
Copper-Catalyzed Alkenylation of Alkylzinc Reagents
0517
1,2-Dicarbofunctionalization of Alkenes in the Presence of Ni(dme)Br2
0518
Diastereoselective Carbocyclization of Enallenes
0519
Decarbonylative Trifluoromethylation of Acid Fluorides
0520
Enantioselective 1,2-Difunctionalization of 1,3-Butadiene
0521
Rhodium-Catalyzed Asymmetric Arylation of Cyclopropenes
0522
A Facile and Efficient Synthesis of Aryl Ethers from Ammonium Salts
0523
Synthesis of Ketoester-C- or Acyl-C-Glycosides from Glycopyranosyl Cyanide
0524
Copper-Catalyzed Alkylboration Reaction of Alkenes
0525
Four-Component Dearomative Coupling of Indolylboron Ate Complexes
0526
Synthesis of Terminal Vinylindoles
0527
Nickel-Catalyzed Tandem Cyclizations

Organo- and Biocatalysis

z0529
All PDFs of this category
0529
Enantioselective Cyclization by a Hexacoordinated Chiral Hydrogen Phosphate
0530
Temperature-Directed Biocatalysis for the Production of Aromatic Aldehydes
0531
Conjugate Reductions of Carbonyl Compounds with Diazaphospholenes
0532
Enzymatic Kinetic Resolution of Secondary Thiols
0533
Kinetic Resolution of Alcohols by Using a Recyclable Isothiourea Catalyst
0534
Linked Dianionic Phase-Transfer Catalyst for Asymmetric Fluorocyclization
0535
Stereoselective Enzymatic Synthesis of Heteroatom-Substituted Cyclopropanes
0536
Intermolecular [4+2] Cycloadditions Catalyzed by an Artificial Enzyme Like Capsule

Polymer-Supported Synthesis

z0537
All PDFs of this category
0537
Mechanochemical Generation of HCN from K3[Fe(CN)6]: A Novel Strecker Protocol
0538
A 1,5-Diazacyclooctane Derivative for the Preparation of a Nanoparticulate Pd Catalyst
0539
Azide–Alkyne Cycloaddition in Water on Heterogeneous Copper Catalysts
0540
Suzuki Coupling on a Hydrotalcite-Supported Pd(0) Catalyst
0541
Dehydrogenative Biaryl Coupling on a Molybdenum Anode
0542
Homo- and Cross-Coupling of Terminal Alkynes on a Copper/Carbon Nitride Catalyst
0543
Transamidation of Aliphatic Amides on Graphene Oxide
0544
Olefin Epoxidation on Ruthenium-Exchanged Hydroxyapatite
0545
Chemoselective Hydrogenation of Aldehydes on an Iron Pincer Complex Catalyst
0546
Textile-Supported Silver Nanoparticles for Nitroaromatic Reduction
0547
Knoevenagel Condensation on an Aminofunctionalized Metal-Organic Framework
0548
Cycloaddition of Diynes and Alkynes Catalyzed by a Co-Based Metal-Organic Framework
0549
Cross-Coupling of Aroyl Chlorides with Alkynes on Cu2O/SiO2-Eggshell
0550
Preparation of 2,3-Dihydroperimidines on Nanoparticulate γ-Al2O3/SbCl5

Erratum

0551
Nicolle, S. M.; Nortcliffe, A.; Bartrum, H. E.; Lewis, W.; Hayes, C. J.; Moody, C. J.: Synthesis of Functionalized Spiro-Oxetanes for Combinatorial Chemistry