Glutaraldehyde Derivatives as Building Blocks for Stereoselective (Z)-C5 Elongation of a Regular Isoprenoid Chain

N. Ya Grigorieva; O. N. Yudina; A. M. Moiseenkov

doi:10.1055/s-1989-27327

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Synthesis 1989; 1989(8): 591-595
DOI: 10.1055/s-1989-27327

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Glutaraldehyde Derivatives as Building Blocks for Stereoselective (Z)-C₅ Elongation of a Regular Isoprenoid Chain

N. Ya. Grigorieva^* , O. N. Yudina, A. M. Moiseenkov

^*N. D. Zelinsky Institute of Organic Chemistry, Academy of Sciences, Moscow, USSR

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Publication Date:
17 September 2002 (online)

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5,5-Ethylenedioxypentanal and its tert-butylimine may serve as versatile non-isoprenoid synthons for the construction of a regular cisoid terpenoid chain using the controlled crossed aldol condensation methodology.