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Synthesis 1992; 1992(8): 749-750
DOI: 10.1055/s-1992-26215
short paper
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N-(Trifluoromethylsulfonyl)arenesulfonimidoyl and N,N′-Bis(trifluoromethylsulfonyl)arenesulfonodiimidoyl Chlorides

L. M. Yagupolskii* , R. Yu. Garlyauskajte, N. V. Kondratenko
  • *Institute of Organic Chemistry of the Ukrainian Academy of Sciences, 252094, Kiev, Ukraine
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Publication Date:
17 September 2002 (online)

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N-(Trifluoromethylsulfonyl)arenesulfonimidoyl chlorides 3a-e and N,N′-bis(trifluoromethylsulfonyl)arenesulfonodiimidoyl chlorides 6a-e are obtained by N,N-dichlorotrifluoromethanesulfonamide oxidative imination of arene sulfonyl chlorides 1a-e and diaryl disulfides 4a-e, respectively. The electron nature of the new substituents possessing high electron-accepting ability is also determined.