Metal Ion-Mediated Heteroatom Cyclisations. Application of Aryl/Alkenyl  Palladium(II)-Based Electrophilic Triggers

Ian W. Davies; David I. C. Scopes; Timothy Gallagher

doi:10.1055/s-1993-22359

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Synlett 1993; 1993(1): 85-87
DOI: 10.1055/s-1993-22359

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Metal Ion-Mediated Heteroatom Cyclisations. Application of Aryl/Alkenyl Palladium(II)-Based Electrophilic Triggers

Ian W. Davies^* , David I. C. Scopes, Timothy Gallagher

^*School of Chemistry, Bath University, Bath BA2 7AY, England

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Publication Date:
19 March 2002 (online)

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Reaction of N-substituted allenic amines (4) with a modified palladium(II) electrophile, generated in situ from Pd(0) and either an aryl or alkenyl halide, allows heteroatom cyclisation to be efficiently combined with a sp²-sp² coupling step leading to pyrrolidines (5) and (6).

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