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Synlett 1993; 1993(10): 745-747
DOI: 10.1055/s-1993-22593
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Stereoselective Synthesis of cis-Fused Bicyclic α-(Z)-Chloroalkylidene-γ-butyrolactone Derivatives via the Cascade Carbopalladation Cyclization Reaction

Jianguo Ji* , Xiyan Lu
  • *Shanghai Institute of Organic Chemistry, Academia Sinica, 345 Lingling Lu, Shanghai 200032, China
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Publication Date:
19 March 2002 (online)

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Palladium dichloride catalysed cascade cyclization of 1,5-hexadien-3-yl 2-alkynoates in the presence of CuCl2 and LiCl provides a facile access to cis-fused bicyclic α-(Z)-chloroalkylidene-γ-butyrolactone derivatives.

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