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Synlett 1993; 1993(12): 895-896
DOI: 10.1055/s-1993-22642
DOI: 10.1055/s-1993-22642
letter
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A Simple Enantioselective Synthesis of (-)-S- and (+)-R-Camphonanic Acids
Further Information
Publication History
Publication Date:
19 March 2002 (online)
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A four step enantioselective synthesis of 1S- and 1R-1,2, 2-trimethylcyclopentanecarboxylic acids [(S)- and (R)-camphonanic acid, (-)-1 and (+)-1 respectively] has been achieved from ß-cyclogeraniol, using a Katsuki-Sharpless asymmetric epoxidation and a pinacollic rearrangement as key synthetic steps.