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Synlett 1995; 1995(3): 277-279
DOI: 10.1055/s-1995-4927
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Synthesis of the Bicyclic Moiety of the Miharamycins by Samarium (II) Iodide Induced Ring Closure

Antony J. Fairbanks, Pierre Sinaÿ*
  • *Ecole Normale Supérieure, Département de Chimie, associé au CNRS, 24 rue Lhomond, 75231 Paris Cedex 05, France
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Publication History

Publication Date:
31 December 2000 (online)

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The bicyclic carbohydrate moiety of miharamycins (A and B) was constructed through intramolecular reductive cyclisation of a ketosugar with an appropriate ethynic appendage.

Miharamycins - Samarium (II) Iodide - Radical Cyclisation