Download PDF
Synlett 1995; 1995(6): 645-646
DOI: 10.1055/s-1995-5042
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Umpolung Addition Reaction of Nucleophiles to 2,3-Butadienoates Catalyzed by a Phosphine

Chunming Zhang, Xiyan Lu*
  • *Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai 200032, China, Fax: 86-21-4166128
Further Information

Publication History

Publication Date:
31 December 2000 (online)

  PDF Download  Permissions and Reprints All articles of this category

Addition of carbon and oxygen nucleophiles to 2,3-butadienoates under the catalysis of a phosphine gave inverse addition products regioselectively. The mechanism is briefly discussed.

nucleophile - 2,3-butadienoates - phosphine-catalyzed - umpolung - inverse addition