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Synlett 1997; 1997(2): 183-184
DOI: 10.1055/s-1997-734
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"Constructive" Creation of a Bimetallic Centre via 1,4-Migration of a Trimethylsilyl Group from Oxygen to Carbon

T. N. Mitchell* , M. Schütze1 , F. Gießelmann1
  • *Fachbereich Chemie, Universität Dortmund, D-44221 Dortmund, Germany
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Publication Date:
31 December 2000 (online)

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Treatment of silyl allyl ethers in which the allyl residue contains two stannyl groups or one silyl and one stannyl group leads to 1,4-migration of the silyl residue from oxygen to carbon, thus creating a new bimetallic centre.

1,4-migration - silicon - oxygen - carbon - bimetallic centre