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Synthesis 2009(3): 372-374
DOI: 10.1055/s-0028-1083310
DOI: 10.1055/s-0028-1083310
SHORTPAPER
© Georg Thieme Verlag
Stuttgart ˙ New York
Total Synthesis of (±)-1,3,4,5-Tetragalloylapiitol
Weitere Informationen
Received
29 September 2008
Publikationsdatum:
09. Januar 2009 (online)
Publikationsverlauf
Publikationsdatum:
09. Januar 2009 (online)
Abstract
Starting from citraconic anhydride, the first total synthesis of (±)-1,3,4,5-tetragalloylapiitol has been demonstrated via a stepwise route involving generation of an apiitol derivative followed by benzoylation.
Key words
allylic hydroxylation - osmium tetroxide - natural products - (±)-1,3,4,5-tetragalloylapiitol
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