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Synthesis 2012(5): 653-676
DOI: 10.1055/s-0031-1289686
DOI: 10.1055/s-0031-1289686
REVIEW
© Georg Thieme Verlag
Stuttgart ˙ New York
Decarboxylative Carbon-Carbon Bond-Forming Transformations of (Hetero)aromatic Carboxylic Acids
Further Information
Received
2 November 2011
Publication Date:
03 February 2012 (online)
Publication History
Publication Date:
03 February 2012 (online)
Abstract
In the last decade, the use of (hetero)aromatic carboxylic acids as aryl donors in C-C bond-forming reactions has emerged as a powerful tool for organic synthesis. In this review article we describe the progress that has been achieved in the coupling of these acids with (pseudo)haloarenes, arenes, alkenes and alkynes, among other coupling partners, with particular emphasis on the most recent developments.
1 Introduction
2 Decarboxylative Cross-Couplings
3 Oxidative Decarboxylative Cross-Couplings
4 Miscellaneous Decarboxylative Transformations
5 Conclusions
Key words
carboxylic acids - decarboxylation - cross-coupling - palladium - catalysis
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References
Other types of carboxylic acids have also been used in carbon-carbon bond-forming reactions (e.g., propargylic, aliphatic or 2-oxo carboxylic acids - see ref. 2), however this review will focus on the use of(hetero)aromatic carboxylic acids.