Subscribe to RSS
Please copy the URL and add it into your RSS Feed Reader.
https://www.thieme-connect.de/rss/thieme/en/10.1055-s-00000083.xml
Synlett 2012(8): 1154-1169
DOI: 10.1055/s-0031-1290665
DOI: 10.1055/s-0031-1290665
ACCOUNT
© Georg Thieme Verlag
Stuttgart ˙ New York
How Not to Discover a New Reagent. The Evolution and Chemistry of Woollins’ Reagent
Further Information
Received
21 November 2011
Publication Date:
26 April 2012 (online)
Publication History
Publication Date:
26 April 2012 (online)
Abstract
The pathways in research can be complex. This review provides a personal account of the winding scientific and funding road that led to Woollins’ reagent. The synthesis and applications of Woollins’ reagent are summarised.
Key words
heterocycles - phosphorus - selenium - group 16
- 1
Goehring M.Debo A. Z. Anorg. Allg. Chem. 1953, 273: 319 - 2
Daum KW.Goehring M.Weiss J. Z. Anorg. Allg. Chem. 1955, 278: 260 - 3
Piper TS. J. Am. Chem. Soc. 1958, 80: 30 - 4
Woollins JD.Grinter R.Johnson MK.Thomson AJ. J. Chem. Soc., Dalton Trans. 1980, 1910 - 5
Powell DB.Woollins JD. Spectrochim. Acta, Part A 1980, 36: 447 -
6a
Ghosh AK.Bilcer G.Schiltz G. Synthesis 2001, 2203 -
6b
List B.Castello C. Synlett 2001, 1687 - 7
Irgolic KJ. In Houben-Weyl 4th ed., Vol. E12b:Klamann D. Thieme; Stuttgart: 1990. p.150 - 8 For a review, see:
Labes MM.Love P.Nichols LF. Chem. Rev. 1979, 79: 1 - 9
Chivers T. Chem. Rev. 1985, 85: 341 - 10
Chivers T. A Guide to Chalcogen-Nitrogen Chemistry World Scientific; Singapore: 2005. -
11a
Morris JL.Rees CW. Chem. Soc. Rev. 1986, 1 -
11b
Rees CW. J. Heterocycl. Chem. 1992, 29: 639 - 12
Nikonov GN.Balueva AS. In Comprehensive Heterocyclic Chemistry II Vol. 9:Katritsky AR.Rees CW.Scriven EFV.Newkome GR. Pergamon/Elsevier; Oxford: 1996. - 13
Kelly PF.Woollins JD. Polyhedron 1986, 5: 607 - 14
Chivers T.Edelmann F. Polyhedron 1986, 5: 1661 - 15
Kelly PF.Slawin AMZ.Williams DJ.Woollins JD. Chem. Soc. Rev. 1992, 246 -
16a
Jones R.Kelly PF.Warrens CP.Williams DJ.Woollins JD. J. Chem. Soc., Chem. Comm. 1986, 711 -
16b
Jones R.Warrens CP.Williams DJ.Woollins JD. J. Chem. Soc., Dalton Trans. 1987, 907 -
16c
Jones R.Kelly PF.Williams DJ.Woollins JD. J. Chem. Soc., Dalton Trans. 1988, 803 -
17a
Kelly PF.Slawin AMZ.Williams DJ.Woollins JD. J. Chem. Soc., Chem. Commun. 1989, 408 -
17b
Kelly PF.Parkin IP.Slawin AMZ.Williams DJ.Woollins JD. Angew. Chem. Int. Ed. Engl. 1989, 28: 1047 -
17c
Kelly PF.Slawin AMZ.Williams DJ.Woollins JD. Polyhedron 1990, 9: 1567 - 18
Kelly PF.Slawin AMZ.Williams DJ.Woollins JD. Angew. Chem. Int. Ed. Engl. 1992, 31: 616 -
19a
Kelly PF.Slawin AMZ.Williams DJ.Woollins JD. Polyhedron 1991, 10: 2337 -
19b
Ginn VC.Kelly PF.Slawin AMZ.Williams DJ.Woollins JD. J. Chem. Soc., Dalton Trans. 1992, 963 - 20
Roesky HW.Rao MNS.Nakajima T.Sheldrick WS. Chem. Ber. 1979, 112: 3351 - 21
Belton PS.Ginn VC.Kelly PF.Woollins JD.
J. Chem. Soc., Dalton Trans. 1992, 1135 - 22
Menzer S.Phillips JR.Slawin AMZ.Williams DJ.Woollins JD. J. Chem. Soc., Dalton Trans. 2000, 3269 - 23
Phillips JR.Poat JC.Slawin AMZ.Williams DJ.Wood PT.Woollins JD. J. Chem. Soc., Dalton Trans. 1995, 2369 - 24
Poat JC.Slawin AMZ.Williams DJ.Wood PT.Woollins JD. J. Chem. Soc., Chem. Commun. 1990, 1036 - 25
Poat JC.Slawin AMZ.Williams DJ.Wood PT.Woollins JD. Polyhedron 1992, 11: 2125 -
26a
Belton PS.Parkin IP.Williams DJ.Woollins JD. J. Chem. Soc., Chem. Commun. 1988, 1479 -
26b
Parkin IP.Williams DJ.Woollins JD. J. Chem. Soc., Chem. Commun. 1989, 58 -
26c
Parkin IP.Woollins JD.
J. Chem. Soc., Dalton Trans. 1990, 925 - 27
Jagg PN.Kelly PF.Rzepa HS.Williams DJ.Woollins JD.Wylie W. J. Chem. Soc., Chem. Commun. 1991, 942 - 28
Meisel M.Grunze G. Z. Anorg. Allg. Chem. 1970, 373: 265 - 29
Slawin AMZ.Williams DJ.Wood PT.Woollins JD. J. Chem. Soc., Chem. Commun. 1987, 1741 -
30a
Kilian P.Knight FR.Woollins JD. Chem. Eur. J. 2011, 17: 2302 -
30b
Kilian P.Knight FR.Woollins JD. Coord. Chem. Rev. 2011, 255: 1387 - 31
Kilian P.Philp D.Slawin AMZ.Woollins JD. Eur. J. Inorg. Chem. 2003, 249 - 32
Kilian P.Slawin AMZ.Woollins JD. Chem. Eur. J. 2003, 9: 215 -
33a
Kilian P.Slawin AMZ.Woollins JD. Chem. Commun. (Cambridge) 2003, 1174 -
33b
Kilian P.Milton HL.Slawin AMZ.Woollins JD. Inorg. Chem. 2004, 43: 2252 -
34a
Kilian P.Slawin AMZ.Woollins JD. Dalton Trans. 2006, 2175 -
34b
Somisara DMUK.Bühl M.Lebl T.Richardson NV.Slawin AMZ.Woollins JD.Kilian P. Chem. Eur. J. 2010, 17: 2666 -
35a
Knight FR.Fuller AR.Bühl M.Slawin AMZ.Woollins JD. Chem. Eur. J. 2010, 16: 7503 -
35b
Knight FR.Fuller AR.Bühl M.Slawin AMZ.Woollins JD. Chem. Eur. J. 2010, 16: 7605 -
35c
Knight FR.Fuller AR.Bühl M.Slawin AMZ.Woollins JD. Chem. Eur. J. 2010, 16: 7617 -
35d
Knight FR.Fuller AR.Bühl M.Slawin AMZ.Woollins JD. Inorg. Chem. 2010, 49: 7577 -
36a
Aschenbach LK.Knight FR.Randall RAM.Cordes DB.Baggott A.Bühl M.Slawin AMZ.Woollins JD. Dalton Trans. 2012, 41: 3141 -
36b
Knight FR.Arachchige KSA.Randall RAM.Bühl M.Slawin AMZ.Woollins JD. Dalton Trans. 2012, 41: 3154 -
37a
Fitzmaurice JC.Williams DJ.Wood PT.Woollins JD. J. Chem. Soc., Chem. Commun. 1988, 741 -
37b
Wood PT.Woollins JD. J. Chem. Soc., Chem. Commun. 1988, 1190 -
37c
Wood PT.Woollins JD. Phosphorus, Sulfur Silicon Relat. Elem. 1989, 41: 51 -
37d
Pilkington MJ.Slawin AMZ.Williams DJ.Wood PT.Woollins JD. Heteroat. Chem. 1990, 1: 351 -
38a
Karaghiosoff K.Jochem G. Phosphorus, Sulfur Silicon Relat. Elem. 1989, 41: 460 -
38b
Karaghiosoff K.Eckstein K.Motzer R. Phosphorus, Sulfur Silicon Relat. Elem. 1994, 93: 185 -
38c
Karaghiosoff K. Habilitation thesis University of Munich; Germany: 1997. -
38d
Großman G.Ohms G.Kruger K.Karaghiosoff K.Eckstein K.Hahn J.Hopp A.Malkina OL.Hrobarik P. Z. Anorg. Allg. Chem. 2001, 627: 1269 - 39
Hall SW.Pilkington MJ.Slawin AMZ.Williams DJ.Woollins JD. Polyhedron 1991, 10: 261 - 40
Parkin IP.Pilkington MJ.Slawin AMZ.Williams DJ.Woollins JD. Polyhedron 1990, 9: 987 - 41
Woollins JD. J. Chem. Soc., Dalton Trans. 1996, 2893 - 42
Ly TQ.Slawin AMZ.Woollins JD. Angew. Chem., Int. Ed. 1998, 37: 2501 -
43a
Foreman MRSt. J.Slawin AMZ.Woollins JD. J. Chem. Soc., Dalton Trans. 1999, 1175 -
43b
Foreman MRSt. J.Slawin AMZ.Woollins JD. J. Chem. Soc., Dalton Trans. 1996, 3653 -
43c
Foreman MRSt. J.Slawin AMZ.Woollins JD. Chem. Commun. (Cambridge) 1997, 1269 -
43d
Foreman MRSt. J.Slawin AMZ.Woollins JD. Chem. Commun. (Cambridge) 1997, 855 - 44
Baxter I.Hill AF.Malget JM.White AJP.Williams DJ. Chem. Commun. (Cambridge) 1997, 2049 - 45
Gray IP.Bhattacharyya P.Slawin AMZ.Woollins JD. Chem. Eur. J. 2005, 11: 6221 - 46
Parveen S.Kilian P.Slawin AMZ.Woollins JD. Dalton Trans. 2006, 2586 - 47
Kilian P.Slawin AMZ.Woollins JD. Chem. Commun. (Cambridge) 2001, 2288 -
48a
Cava MP.Levinson MI. Tetrahedron 1985, 41: 5061 -
48b
Cherkasov RA.Kutyrev GA.Pudovik AN. Tetrahedron 1985, 41: 2567 -
49a
Rothenberger A.Shi W.Shafaei-Fallah M. Chem. Eur. J. 2007, 13: 5974 -
49b
Shi W.Shafaei-Fallah M.Rothenberger A. Chem. Commun. (Cambridge) 2007, 4255 -
49c
Shi W.Zhang L.Shafaei-Fallah M.Rothenberger A. Z. Anorg. Allg. Chem. 2007, 633: 440 -
49d
Shi W.Shafaei-Fallah M.Zhang L.Anson CE.Matern E.Rothenberger A. Chem. Eur. J. 2007, 13: 598 -
50a
Gray IP.Slawin AMZ.Woollins JD. Dalton Trans. 2005, 2188 -
50b
Hua G.Randall RAM.Slawin AMZ.Woollins JD. Z. Anorg. Allg. Chem. 2011, 637: 1800 - 51
Hua G.Woollins JD. Organic Phosphorus-Selenium Chemistry, In Selenium and Tellurium ChemistryWoollins JD.Laitinen R. Springer; Berlin: 2011. Chap. 1. - 52
Hua G.Woollins JD. Angew. Chem. Int. Ed. 2009, 48: 1368 - 53
Hua G.Li Y.Slawin AMZ.Woollins JD. Org. Lett. 2006, 8: 5251 - 54
Bethke J.Karaghiosoff K.Wessjohann LA. Tetrahedron Lett. 2003, 44: 6911 - 55
Bhattacharyya P.Woollins JD. Tetrahedron Lett. 2001, 42: 5949 - 56
Li Y.Hua G.Slawin AMZ.Woollins JD. Molecules 2009, 14: 884 - 57
Hua G.Li Y.Slawin AMZ.Woollins JD. Dalton Trans. 2007, 1477 - 58
Bhattacharyya P.Slawin AMZ.Woollins JD. J. Chem. Soc., Dalton Trans. 2001, 300 - 59
Bhattacharyya P.Slawin AMZ.Woollins JD. Chem. Eur. J. 2002, 8: 2705 - 60
Hua G.Li Y.Slawin AMZ.Woollins JD. Chem. Commun. (Cambridge) 2007, 1465 - 61
Bhattacharyya P.Slawin AMZ.Woollins JD. Angew. Chem. Int. Ed. 2000, 39: 1973 - 62
Hua G.Henry JB.Li Y.Mount AR.Slawin AMZ.Woollins JD. Org. Biomol. Chem. 2010, 8: 1655 - 63
Hua G.Li Y.Fuller AL.Slawin AMZ.Woollins JD. Eur. J. Org. Chem. 2009, 1612 -
64a
Bhattacharyya P.Slawin AMZ.Woollins JD.
J. Organomet. Chem. 2001, 623: 116 -
64b
Hua G.Fuller AL.Li Y.Slawin AMZ.Woollins JD. New J. Chem. 2010, 34: 1565 -
65a
Hua G.Li Y.Slawin AMZ.Woollins JD. Angew. Chem. Int. Ed. 2008, 47: 2857 -
65b
Hua G.Li Y.Fuller AL.Slawin AMZ.Woollins JD. Eur. J. Org. Chem. 2010, 2607 -
65c
Hua G.Li Y.Slawin AMZ.Woollins JD. Tetrahedron 2008, 64: 5442 - 66
Hua G.Li Y.Slawin AMZ.Woollins JD. Polyhedron 2011, 30: 805 - 67
Hua G.Fuller AL.Bühl M.Slawin AMZ.Woollins JD. Eur. J. Org. Chem. 2011, 3067 - 68
Hua G.Griffin JM.Ashbrook SE.Slawin AMZ.Woollins JD. Angew. Chem. Int. Ed. 2011, 50: 4123