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Synthesis 2012; 44(15): 2333-2339
DOI: 10.1055/s-0031-1290764
DOI: 10.1055/s-0031-1290764
practical synthetic procedures
Regio- and Stereoselective Multicomponent Coupling Reaction of Alkynes and Dimethylzinc Involving Allylnickelacycles
Further Information
Publication History
Received: 10 February 2012
Accepted: 17 February 2012
Publication Date:
12 April 2012 (online)
Abstract
Nickel catalyzes the multicomponent coupling reaction of vinyl epoxides, alkynes, and dimethylzinc to provide hepta-2,5-dienyl alcohols as a mixture of E- and Z-isomers in high yields. Vinylcyclopropane participates in a similar multicomponent coupling reaction to afford dimethyl α-(hepta-2,5-dienyl)malonates with excellent E-stereoselectivity.
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