Synthesis 2012; 44(24): 3805-3810
DOI: 10.1055/s-0032-1317517
paper
© Georg Thieme Verlag Stuttgart · New York

Palladium-Catalyzed Synthesis of Mono- and Diphosphorylated 1,10-Phenanthrolines

Alexandre Mitrofanov
a   Institut de Chimie Moléculaire de l’Université de Bourgogne (ICMUB) - UMR 6302 CNRS, 9 Av. Alain Savary, 21000 Dijon, France   Phone: +33(3)80396117   Email: Roger.Guilard@u-bourgogne.fr
b   Department of Chemistry, Moscow State University, Leninskie Gory, GSP-1, 119991 Moscow, Russian Federation
,
Alla Bessmertnykh Lemeune
a   Institut de Chimie Moléculaire de l’Université de Bourgogne (ICMUB) - UMR 6302 CNRS, 9 Av. Alain Savary, 21000 Dijon, France   Phone: +33(3)80396117   Email: Roger.Guilard@u-bourgogne.fr
,
Christine Stern
a   Institut de Chimie Moléculaire de l’Université de Bourgogne (ICMUB) - UMR 6302 CNRS, 9 Av. Alain Savary, 21000 Dijon, France   Phone: +33(3)80396117   Email: Roger.Guilard@u-bourgogne.fr
,
Roger Guilard*
a   Institut de Chimie Moléculaire de l’Université de Bourgogne (ICMUB) - UMR 6302 CNRS, 9 Av. Alain Savary, 21000 Dijon, France   Phone: +33(3)80396117   Email: Roger.Guilard@u-bourgogne.fr
,
Nataliya Gulyukina
b   Department of Chemistry, Moscow State University, Leninskie Gory, GSP-1, 119991 Moscow, Russian Federation
c   Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninsky Pr. 31, 119991 Moscow, Russian Federation   Fax: +7(495)9393618   Email: beletska@org.chem.msu.ru
,
Irina Beletskaya*
b   Department of Chemistry, Moscow State University, Leninskie Gory, GSP-1, 119991 Moscow, Russian Federation
c   Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninsky Pr. 31, 119991 Moscow, Russian Federation   Fax: +7(495)9393618   Email: beletska@org.chem.msu.ru
› Author Affiliations
Further Information

Publication History

Received: 27 September 2012

Accepted after revision: 10 October 2012

Publication Date:
05 November 2012 (online)


Abstract

A general protocol for the coupling of mono- and dihalo-1,10-phenanthrolines with diethyl phosphite is reported. This reaction proceeds smoothly in the presence of a Pd(OAc)2/dppf catalytic system and triethylamine as a base.

Supporting Information