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Synthesis 2014; 46(03): 295-300
DOI: 10.1055/s-0033-1338571
DOI: 10.1055/s-0033-1338571
paper
Benzoquinone-Promoted Aerobic Oxidative Hydroxylation of Arylboronic Acids in Water
Further Information
Publication History
Received: 10 October 2013
Accepted after revision: 18 November 2013
Publication Date:
05 December 2013 (online)
Abstract
A general and efficient aerobic oxidative hydroxylation of arylboronic acids promoted by benzoquinone in water was realized, and provided phenols in 72–95% yields for 20 examples. The main advantages of this protocol are the use of water as solvent in the presence of a catalytic amount of benzoquinone, and metal-free conditions.
Supporting Information
- for this article is available online at http://www.thieme-connect.com/ejournals/toc/synthesis.
- Supporting Information
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