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Synthesis 2014; 46(17): 2297-2304
DOI: 10.1055/s-0033-1338630
DOI: 10.1055/s-0033-1338630
special topic
Silver-Mediated Alkyne Annulations by C–H/P–H Functionalizations: Step-Economical Access to Benzophospholes
Further Information
Publication History
Received: 01 March 2014
Accepted: 03 April 2014
Publication Date:
30 April 2014 (online)
Abstract
Silver-mediated alkyne annulations by secondary phosphine oxides (SPOs) or arylphosphinates via C–H/P–H functionalization provided versatile access to substituted benzo[b]phospholes in a step-economical fashion.
Supporting Information
- for this article is available online at http://www.thieme-connect.com/ejournals/toc/synthesis.
- Supporting Information
-
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For a recent review, see:
For selected examples, see:
For selected recent reviews on C–H functionalizations, see:
For selected recent reviews on metal-catalyzed oxidative alkyne annulations, see:
For selected examples, see:
Recent examples: rhodium catalysis:
Ruthenium catalysis:
Palladium catalysis:
Representative examples:
Reviews:
Two related studies were reported during the preparation of this manuscript, see: