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Synthesis 2014; 46(20): 2751-2756
DOI: 10.1055/s-0033-1338661
DOI: 10.1055/s-0033-1338661
paper
Asymmetric Transfer Hydrogenation of 3-(Trifluoromethyl)quinolines
Further Information
Publication History
Received: 26 May 2014
Accepted after revision: 25 June 2014
Publication Date:
24 July 2014 (online)
Abstract
A chiral phosphoric acid-catalyzed asymmetric transfer hydrogenation of 3-(trifluoromethyl)quinolines was successfully developed with up to 98% ee. The new method provides a direct and facile access to chiral 2,3-disubstituted 1,2,3,4-tetrahydroquinoline derivatives containing a stereogenic trifluoromethyl group.
Supporting Information
- for this article is available online at http://www.thieme-connect.com/products/ejournals/journal/ 10.1055/s-00000084.
- Supporting Information
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For recent reviews, see:
For reviews, see:
For selected examples, see references 8, 9 and:
For recent reviews on asymmetric reactions using HEH as hydrogen source, see:
For recent reviews, see:
For selected examples on asymmetric reduction of quinolines, see references 11a,b,i,j and: