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Synthesis 2013; 45(20): 2769-2812
DOI: 10.1055/s-0033-1339479
DOI: 10.1055/s-0033-1339479
review
Recent Advances in Metal-Catalyzed Asymmetric Mannich Reactions
Further Information
Publication History
Received: 25 April 2013
Accepted after revision: 12 June 2013
Publication Date:
17 September 2013 (online)
Abstract
In this review, recent works on metal-catalyzed asymmetric Mannich, aza-Henry and vinylogous Mannich reactions are described. The asymmetric Mannich reaction is one of the most powerful methodologies among the carbon–carbon bond-forming reactions, and provides direct access to a wide range of optically active natural products with useful biological properties.
1 Introduction
2 Catalytic Asymmetric Mannich Reactions
2.1 BINOL Ligands
2.2 BINAP Ligands
2.3 Bisoxazoline Ligands
2.4 Pyridine Bisoxazoline Ligands
2.5 Diamine Ligands
2.6 P,N-Ligands
2.7 P,S-Ligands
2.8 P,P-Ligands
2.9 N,N-Ligands
2.10 Miscellaneous
3 Asymmetric Aza-Henry Reactions
3.1 BINOL Ligands
3.2 Bisoxazoline Ligands
3.3 N,N-Ligands
3.4 Miscellaneous
4 Asymmetric Vinylogous Mannich Reactions
5 Conclusion
-
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