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Synthesis 2015; 47(01): 71-78
DOI: 10.1055/s-0034-1379163
DOI: 10.1055/s-0034-1379163
paper
Propargylation of Aldehydes Using Potassium Allenyltrifluoroborate
Further Information
Publication History
Received: 28 May 2014
Accepted after revision: 26 August 2014
Publication Date:
25 September 2014 (online)
Abstract
The commercially available resin Amberlyst A-31 was efficiently used to promote the propargylation of aldehydes using potassium allenyltrifluoroborate. The method is simple and fast, and the products were obtained in short reaction times in high yields and purity at room temperature in a regio- and chemoselective manner.
Supporting Information
- for this article is available online at http://www.thieme-connect.com/products/ejournals/journal/ 10.1055/s-00000084. Included are additional experimental procedures and 1H, 13C, 19F, and 11B NMR for all synthesized compounds.
- Supporting Informtion
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