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Synthesis 2019; 51(17): 3313-3319
DOI: 10.1055/s-0037-1611787
DOI: 10.1055/s-0037-1611787
paper
Copper-Catalyzed Deoxygenative C2-Sulfonylation of Quinoline N-Oxides with DABSO and Phenyldiazonium Tetrafluoroborates for the Synthesis of 2-Sulfonylquinolines via a Radical Reaction
We gratefully acknowledge the financial support from the National Natural Science Foundation of China (21402103, 21772107), the China Postdoctoral Science Foundation (150030), and the Research Fund of Qingdao Agricultural University’s Highlevel Person (631303).Further Information
Publication History
Received: 14 February 2019
Accepted after revision: 14 March 2019
Publication Date:
15 May 2019 (online)
◊ These authors contributed equally to this article.
Abstract
An efficient and practical method for the synthesis of 2-sulfonylquinolines through copper-catalyzed deoxygenative C2-sulfonylation of quinoline N-oxides with 1,4-diazabicyclo[2.2.2]octane bis(sulfur dioxide) (DABSO) and phenyldiazonium tetrafluoroborates is demonstrated. Products with various substituents were obtained in moderate to high yields.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0037-1611787.
- Supporting Information
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