Download PDF
Synthesis 1973; 1973(1): 1-24
DOI: 10.1055/s-1973-22123
review
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Novel Applications of Free-Radical Reactions in Preparative Organic Chemistry

Francesco MINISCI*
  • *Istituto di Chimica del Politecnico, Piazza da Vinci 32, Milano, Italia
Further Information

Publication History

Publication Date:
12 September 2002 (online)

  PDF Download  Permissions and Reprints All articles of this category

The following reactions are described in which the synthetic interest is predominantly determined by the polar characteristics of the radicals and substrates involved: 1. Homolytic Amination of Aromatic Compounds 1.1. Amination with N-Chloroalkylamines 1.2. Amination with Hydroxylamine and Hdroxylamie-O-sulfonic Acid 2. Homolytic Substitution of Protonated Heteroaromatic Bases 2.1. Homolytic Alkylation 2.2. Homolytic Acylation 2.3. Homolytic α-Oxyalkylation 2.4. Homolytic Aminocarbonylation and α-Amidoalkylation 3. Selective Halogenation of Saturated Aliphatic Compounds 4. Alternating Addition of C-Radicals to Conjugated Olefins