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Synthesis 1987; 1987(4): 373-377
DOI: 10.1055/s-1987-27949
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Palladium-Catalyzed Cross-Coupling Reaction of (1-Ethoxy-1-alken-2-yl)boranes With ortho-Functionalized Iodoarenes. A Novel and Convenient Synthesis of Benzo-Fused Heteroaromatic Compounds

Makoto Satoh* , Norio Miyaura, Akira Suzuki
  • *Department of Applied Chemistry, Faculty of Engineering, Hokkaido University, Sapporo 060, Japan
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Publication Date:
20 August 2002 (online)

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ortho-Functionalized styryl ethers are obtained in high yields by palladium-catalyzed cross coupling between (1-ethoxy-1-alken-2-yl)boranes and aryl halides. These styryl ethers are converted to benzo-fused heteroaromatic compounds by cyclodehydration.