Titanium Induced Coupling of Imines to Symmetrical Vicinal (R*,R*)-Diamines

P. Mangeney; T. Tejero; A. Alexakis; F. Grosjean; J. Normant

doi:10.1055/s-1988-27536

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Synthesis 1988; 1988(3): 255-257
DOI: 10.1055/s-1988-27536

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Titanium Induced Coupling of Imines to Symmetrical Vicinal (R,R)-Diamines

P. Mangeney^* , T. Tejero, A. Alexakis, F. Grosjean, J. Normant

^*Laboratoire de Chimie des Organo-éléments, tour 45, Université P. et M. Curie, 4 place Jussieu, F-75252 Paris CEDEX 05, France

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Publication Date:
20 August 2002 (online)

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Symmetrical vicinal (R*,R*)-d,l-diamines were prepared from the corresponding imines and low valent titanium species generated by the action of titanium tetrachloride on amalgamated magnesium.