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Synlett 1990; 1990(10): 629-630
DOI: 10.1055/s-1990-21192
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Carbohydrates as Chiral Templates: Stereoselective Synthesis of (R)-Homoallyl Amines Using L-Fucose as the Auxiliary Formally Enantiomeric to D-Galactose

Sabine Laschat* , Horst Kunz
  • *Institut für Organische Chemie der Universität Mainz, Becherweg 18-22, D-6500 Mainz, Federal Republic of Germany
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Publication Date:
08 March 2002 (online)

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(R)-Homoallyl amines are synthesized with high asymmetric induction using the diastereoselective Lewis acid induced addition of allylsilanes and allylstannanes to Schiff bases of O-acyl protected fucopyranosylamine.