Download PDF
Synthesis 1990; 1990(8): 661-663
DOI: 10.1055/s-1990-26973
paper
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

The Preparation and the Use of 2-Chloro-2,4-dioxo-3-methyl-1,3,2-thiazaphospholidine, a Highly Reactive Reagent for the Synthesis of S-(N-Methylcarbamoylmethyl) Dialkyl Thiophosphates and Dialkyl Sodium Phosphates

Wolfgang Richter* , Ivar Ugi
  • *Institut für Organische Chemie der Technischen Universität München, D-8046 Garching, Federal Republic of Germany
Further Information

Publication History

Publication Date:
17 September 2002 (online)

  PDF Download  Permissions and Reprints All articles of this category

The synthesis of 2-chloro-2,4-dioxo-3-methyl-1,3,2-thiazaphospholidine (4), a versatile and highly reactive reagent for the synthesis of unsymmetrical S-(N-methylcarbamoylmethyl) dialkyl thiophosphates and dialkyl sodium phosphates, and several reactions with alcohols are reported.