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Synthesis 1990; 1990(11): 1037-1039
DOI: 10.1055/s-1990-27088
DOI: 10.1055/s-1990-27088
paper
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Stereoselective Synthesis of trans-2-Alkylthiane 1-Oxides
Further Information
Publication History
Publication Date:
17 September 2002 (online)
2-Alkylthianes react with tert-butyl hypochlorite to give trans-1-tert-butoxythianium salts which are hydrolyzed to trans-2-alkylthiane 1-oxides with high stereoselectivity.