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Synthesis 1991; 1991(5): 402-404
DOI: 10.1055/s-1991-26477
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Stereoselective Synthesis of trans-4,5-Substituted 1,4,5,6-tetrahydropyridine-2-(olates)thiolates

A. M. Shestopalov* , V. P. Litvinov, L. A. Rodinovskaya, Yu. A. Sharanin
  • *N. D. Zelinsky Institute of Organic Chemistry, Academy of Sciences, Leninsky Prospect 47, SU-117913 Moscow, USSR
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Publication Date:
29 April 2002 (online)

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trans-4,5-Substituted 1,4,5,6-tetrahydropyridine-2-(olates)thiolates are prepared either from pyridinium salts and cyanoacetic acid derivatives or from pyridinium salts, aromatic aldehydes and ethyl cyanoacetate or cyanoacetamide in the presence of a base.