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Synlett 1994; 1994(2): 121-122
DOI: 10.1055/s-1994-22762
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Reactions of a New Acyl Anion Equivalent; -COCO2R, and Its Use to Preparation of α-Ketoesters.

T. Takahashi* , T. Okano, T. Harada, K. Imamura, H. Yamada
  • *Department of Chemical Engineering, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo 152, JAPAN.
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Publication Date:
22 March 2002 (online)

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Preparation of a new acyl carbanion; t-butyl 2-alkoxy-2-cyanoacetate and its reactions with alkyl halide, aldehyde and acid chloride are described.