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Synlett 1994; 1994(5): 349-350
DOI: 10.1055/s-1994-22850
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Directed ortho Metalation - Cross Coupling Connections. Nickel (0) - Catalyzed Cross Coupling of Aryl Triflates with Organozinc Reagents

C. A. Quesnelle* , O. B. Familoni, V. Snieckus
  • *Guelph-Waterloo Center for Graduate Work in Chemistry, University of Waterloo, Waterloo, Ontario N2L 3G1 Canada
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Publication Date:
22 March 2002 (online)

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Aryl zinc reagents, derived by directed ortho metalation, undergo cross coupling with aryl triflates under Ni(0) catalysis to provide a general, regiospecific method for the synthesis of diverse functionalized biaryls (Table).