Download PDF
Synlett 1994; 1994(6): 413-414
DOI: 10.1055/s-1994-22869
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Planar Chiral Arylaldehydeimine Tricarbonylchromium Complexes in the Asymmetric Baylis - Hillman Coupling Reaction

E. Peter Kündig* , Long He Xu, Barbara Schnell
  • *Département de Chimie Organique, Université de Genève, 30 quai Ernest Ansermet, CH-1211 Genève 4, Switzerland
Further Information

Publication History

Publication Date:
18 September 2002 (online)

  PDF Download  Permissions and Reprints All articles of this category

The DABCO-catalyzed coupling reaction of methyl acrylate and acrylonitrile with enantiomerically pure planar chiral o-substituted (benzaldehyde tosylimine) Cr(CO)3 complexes after metal removal provides chiral amines in high yields and enantiomeric excess.