Download PDF
Synlett 1994; 1994(7): 479-481
DOI: 10.1055/s-1994-22895
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

How Does Chiral Oxo(salen)manganese(V) Complex Discriminate the Enantioface of Simple Olefins? Scope and Limitation of Salen-Catalyzed Epoxidation

Tetsuya Hamada* , Ryo Irie, Tsutomu Katsuki
  • *Department of Chemistry, Faculty of Science, Kyushu University 33, Hakozaki, Higashi-ku, Fukuoka 812, Japan
Further Information

Publication History

Publication Date:
18 September 2002 (online)

  PDF Download  Permissions and Reprints All articles of this category

Enantiofacial selection of simple olefins in salen-catalyzed asymmetric epoxidation was found to be controlled by two factors, repulsive steric interaction and π,π-repulsive electronic interaction.