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Synthesis 1995; 1995(10): 1287-1290
DOI: 10.1055/s-1995-4434
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Boron Trifluoride-Diethyl Ether Complex Catalyzed Aromatic Amino-Claisen Rearrangements

Wayne K. Anderson* , Gaifa Lai
  • *Department of Medical Chemistry, School of Pharmacy, State University of New York at Buffalo, Buffalo, New York 14260, USA
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Publication Date:
31 December 2000 (online)

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Boron trifluoride-diethyl ether complex (BF3⋅OEt2) was demonstrated to be an efficient catalyst for the amino-Claisen rearrangements of various aromatic N-allylamines into the corresponding o-allylamines in moderate yields.

Boron trifluoride-diethyl ether complex promotes amino-Claisen rearrangements of aromatic N-allylamines