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Synlett 1995; 1995(4): 321-322
DOI: 10.1055/s-1995-4972
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[2,3]-Wittig Rearrangement using Glucose as a Chiral Auxiliary: Asymmetric Transmission from the Anomeric Center

Katsuhiko Tomooka, Yoshitaka Nakamura, Takeshi Nakai*
  • *Department of Chemical Technology, Tokyo Institute of Technology, Meguro-ku, Tokyo, Japan
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Publication Date:
31 December 2000 (online)

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The asymmetric [2,3]-Wittig rearrangements of glucose derivatives 3 and 6 were found to proceed with a high degree of asymmetric transmission from the anomeric center.

asymmetric transmission - anomeric center - glucose - [2,3]-Wittig rearrangement