Download PDF
Synlett 1995; 1995(11): 1191-1193
DOI: 10.1055/s-1995-5203
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Electronic versus Steric Effects in 5-endo-trig-like Electrophilic Cyclizations

Yannick Landais* , Denis Planchenault
  • *Institut de Chimie Organique, Université de Lausanne, Collège Propédeutique, 1015 Lausanne-Dorigny, Switzerland, Fax (0)21 692 40 05; ylandais@ulys.unil.ch
Further Information

Publication History

Publication Date:
31 December 2000 (online)

  PDF Download  Permissions and Reprints All articles of this category

Electronically and sterically differentiated allylic substituents such as RO, NHPh, PhS, and PhSO2 groups have been used to demonstrate the influence of electronic and/or steric effects in the stereocontrol of electrophilic 5-endo-trig-like cyclizations of 2-substituted-3-alkenols.

5-endo-trig cyclization - electrophile - allylic - tetrahydrofuran - selenoetherification