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Synlett 1996; 1996(2): 185-186
DOI: 10.1055/s-1996-5346
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Organozinc Reagents for the Nucleophilic C-Glycosylation of Glycals

Simon N. Thorn* , Timothy Gallagher1
  • *School of Chemistry, University of Bristol, Bristol BS8 1TS, United Kingdom
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Publication History

Publication Date:
31 December 2000 (online)

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Addition of a variety of simple and functionalised organozinc reagents (R2Zn or RZnX) to a structurally diverse range of glycals takes place in the presence of either BF3.OEt2 or TMSOTf and efficiently leads to C(1)-glycosides with selectivity for the α-isomer.

C-Glycosides - organozinc reagents - ultrasound