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Synlett 1996; 1996(4): 330-332
DOI: 10.1055/s-1996-5426
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Reactions of Tempo with Alkylsamarium and Other Organometallic Reagents

Tadamichi Nagashima, Dennis P. Curran*
  • *Department of Chemistry, University of Pittsburgh, Pittsburgh, PA 15260, USA
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Publication History

Publication Date:
31 December 2000 (online)

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Reactions of various alkylmetals with Tempo have been studied. Depending on the metal, the alkyl-Temp adduct was obtained in poor to good yield. Alkylsamarium reagents are useful because they are easily to prepare and highly reactive towards Tempo.

Tempo - alkylsamariums - oxidation