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Synlett 1996; 1996(8): 775-776
DOI: 10.1055/s-1996-5512
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Syntheses and Vanadium Complex of Salen-like Bissulfoximines

Carsten Bolm* , Frank Bienewald, Klaus Harms
  • *Fachbereich Chemie der Philipps-Universität Marburg, Hans-Meerwein-Straße, D-35032 Marburg, Germany, Fax (new) (Int.) 241 8888 385, e-mail (new) Carsten.Bolm@RWTH-Aachen.de
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Publication History

Publication Date:
31 December 2000 (online)

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The syntheses of salen-like bissulfoximines are reported. The ability of these compounds to bind transition metals has been demonstrated by the formation of a vanadium(IV) complex. Two X-ray structures reveal the conformational changes of the bissulfoximine upon metal binding.

Sulfoximines - Salen - Vanadium Complexes - Catalysis - Oxidation