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Synlett 1997; 1997(11): 1273-1274
DOI: 10.1055/s-1997-1020
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Palladium-Catalyzed Cross-Coupling Reactions of 3-Tributylstannylsulfolene

Sean P. Bew, J. B. Sweeney*
  • *School of Chemistry, University of Bristol, Cantocks Close, Bristol BS8 1TS, U.K.
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Publication History

Publication Date:
31 December 2000 (online)

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3-Tributylstannylsulfolene (1) undergoes palladium-catalyzed cross-coupling reactions with aryl and vinyl halides, cyclohex-1-enyl triflates and acyl chlorides in moderate to excellent yield, thereby allowing rapid entry to a diverse range of 3-substituted sulfolenes, species known to be reliable precursors to 3-substituted 1,3-dienes.

sulfolenes - Stille - palladium(0)