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Synthesis 1997; 1997(5): 545-548
DOI: 10.1055/s-1997-1218
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A General Synthesis of Amines and Hydrazines by Oxidation of Amidocuprates and Zinc-Amidocuprates

F. Canè1 , D. Brancaleoni2 , P. Dembech3 , A. Ricci4 , G. Seconi1
  • 1Istituto die Composti del Carbonio Contenenti Eteroatomi del CNR, Area di Ricerca di Bologna, Via P. Gobetti 101, I-40129 Bologna, Italia
  • 2Dipartimento di Chimica Organica “A. Mangini”, Facoltà di Chimica Industriale, Via Risorgimento 4, I-40136 Bologna, Italy
  • 3Istituto die Composti del Carbonio Contenenti Eteroatomi del CNR, Area di Ricerca di Bologna, Via P. Gobetti 101, I-40129 Bologna, Italia, Fax +39(51)6398349
  • 4Dipartimento di Chimica Organica “A. Mangini”, Facoltà di Chimica Industriale, Via Risorgimento 4, I-40136 Bologna, Italy, Fax +39(51)6443654
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Publication History

Publication Date:
31 December 2000 (online)

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A wide range of amines and hydrazines were synthesized according to an electrophilic amination protocol by oxidative decomposition of readily generated lithium- and zinc-amidocyanocuprates. Optimization of the yields was achieved by the appropriate combination of the organometallic cluster and the nature of the oxidizing agent.

electrophilic amination - amines - hydrazines - amidocuprates - zinc-amidocuprates oxidates