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Synlett 1997; 1997(7): 777-780
DOI: 10.1055/s-1997-5770
DOI: 10.1055/s-1997-5770
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Homochiral Amine Oxides in the Enantioselective Reduction of Ketones
Further Information
Publication History
Publication Date:
31 December 2000 (online)
The synthesis of a number of novel homochiral prolinol N-oxide derivatives is described. Several of these were found to catalyse the borane reduction of α-chloroacetophenone to (S)-2-chloro-1-phenylethanol in excellent chemical yield and in 96% ee.
chiral amine oxide - enantioselective reduction - borane - chiral alcohol