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Synlett 1998; 1998(5): 525-527
DOI: 10.1055/s-1998-1712
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Generation of 5- and 6-Membered Ring Radicals by Deoxygenation of Alkoxy Radicals

Sunggak Kim* , Dong Hyun Oh
  • *Department of Chemistry, Korea Advanced Institute of Science and Technology, Taejon 305-701, Korea; E-mail: skim@sorak.kaist.ac.kr
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Publication Date:
31 December 2000 (online)

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A new approach, based on deoxygenation of alkoxyl radicals with triphenylphosphine, for the formation of 5- and 6-membered ring radicals from acyclic radical precursors is described.

alkoxy radical - deoxygenation - triphenylphosphine - 5- and 6-membered ring radicals