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Synlett 1998; 1998(9): 991-994
DOI: 10.1055/s-1998-3140
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Studies Towards the Synthesis of the C29-C51 Fragment of Altohyrtin A

Eduardo Fernandez-Megia* , Nelly Gourlaouen, Steven V. Ley, Gareth J. Rowlands
  • *Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, CB2 1EW, UK
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Publication Date:
31 December 2000 (online)

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The synthesis of the highly substituted E and F pyran fragment 23 of altohyrtin A 1 from tri-O-benzyl-d-glucal 5 is described. The synthesis of a model compound 31 containing the altohyrtin A triene side-chain outlines the proposed strategy for the elaboration of the F pyran.

altohyrtin - spongistatin - aldol