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Synlett 1999; 1999(12): 1895-1898
DOI: 10.1055/s-1999-2990
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Tandem (Domino) and Two-Directional Asymmetric Catalysis of Carbonyl-Ene Reaction with Fluoral: Fluoral-Ene Approach to Modeling of Inter-Smectic Layer Interaction of Antiferroelectric Liquid Crystals

Koichi Mikami* , Tomoko Yajima, Nasakul Siree, Masahiro Terada, Yoshiichi Suzuki, Yoichi Takanishi, Hideo Takezoe
  • *Department of Chemical Technology, Tokyo Institute of Technology, Meguro-ku, Tokyo 152-8552, Japan; Fax + 88 3 57 34 27 76; E-mail: kmikami@o.cc.titech.ac.jp
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Publication Date:
31 December 1999 (online)

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A new type of antiferroelectric liquid crystalline molecule of dimeric TFMHPOBO analogue with tri-methylene tether (3-DmTFMHPOBC) was synthesized based on the binaphthol-titanium complex-catalyzed tandem and two-directional fluoral-ene reaction with vinyl sulfides.

fluoral-ene reaction - binaphthol-titanium complex - α-trifluoromethyl carbinols - antiferroelectric liquid crystals - vinyl sulfides